Synthesis of Graphene Oxide using Hummers Method as Adsorbent of Malachite Green Dye
DOI:
https://doi.org/10.26554/ijmr.2023113Keywords:
Graphene Oxide, Malachite Green, AdsorptionAbstract
Graphene oxide materials were successfully synthesized using the Hummer method with XRD, FTIR, and BET characterization results. Graphene oxide material was used as malachite green dye adsorbent. The surface area of graphene oxide material and the maximum adsorption capacity were 157.360 m2/g and 106.383 mg/g. The selectivity process of graphene oxide material to the three dyes showed the most effective malachite green dye. The optimum pH of adsorption was obtained at pH 4. The optimum time of adsorption occurred at 120 minutes and the kinetics model followed PSO. The isotherm data followed Langmuir isotherm and the adsorption process was endoetrmic and spontaneous. The regeneration results showed the ability up to five cycles with a decrease of 40.019% from 96.698% to 56.679%.
References
Ahmad, N., F. S. Arsyad, I. Royani, and A. Lesbani (2023). Charcoal Activated as Template Mg/Al Layered Double Hydroxide for Selective Adsorption of Direct Yellow on Anionic Dyes. Results in Chemistry, 5; 100766
Banda, H., A. Rezk, E. Elsayed, and A. Askalany (2023). Experimental and Computational Study on Utilising Graphene Oxide for Adsorption Cooling and Water Desalination. Applied Thermal Engineering, 229; 120631
Brahma, D., H. Nath, D. Borah, M. Debnath, and H. Saikia (2022). Coconut Husk ash Fabricated CoAl-Layered Double Hydroxide Composite for the Enhanced Sorption of Malachite Green Dye: Isotherm, Kinetics and Thermodynamic Studies. Inorganic Chemistry Communications, 144; 109878
Bulin, C. (2023). Adsorption Mechanism and Removal Efficiency of Magnetic Graphene Oxide Chitosan Hybrid on Aqueous Zn(II). International Journal of Biological Macromolecules, 241; 124588
Buvaneswari, K. and M. Singanan (2022). Removal of Malachite Green Dye in Synthetic Wastewater using Zingiber officinale plant Leaves Biocarbon. Materials Today: Proceedings, 55; 274–279
Chamoli, S., A. Singh, R. K. Kapoor, S. Singh, R. Singh, and J. K. Saini (2023). Purification and Characterization of Laccase from Ganoderma lucidum and its Application in Decolorization of Malachite Green Dye. Bioresource Technology Reports, 21; 101368
Dahlan, I., O. H. Keat, H. A. Aziz, and Y.-T. Hung (2023). Synthesis and Characterization of MOF-5 Incorporated Waste-Derived Siliceous Materials for the Removal of Malachite Green Dye from Aqueous Solution. Sustainable Chemistry and Pharmacy, 31; 100954
Gogoi, K. K. and A. Chowdhury (2019). Electric Field Induced Tunable Memristive Characteristics of Exfoliated Graphene Oxide Embedded Polymer Nanocomposites. Journal of Applied Physics, 126(2); 025501
Gouasmia, A., E. Zouaoui, A. A. Mekkaoui, A. Haddad, and D. Bousba (2022). Highly Efficient Photocatalytic Degradation of Malachite Green Dye Over Copper Oxide and Copper Cobaltite Photocatalysts Under Solar or Microwave Irradiation. Inorganic Chemistry Communications, 145; 110066
Haydari, I., K. Aziz, S. Kaya, T. Daştan, N. Ouazzani, L. Mandi, and F. Aziz (2023). Green Synthesis of Reduced Graphene Oxide and Their Use on Column Adsorption of Phenol from Olive Mill Wastewater. Process Safety and Environmental Protection, 170; 1079–1091
Heshami, M., Z. Tavangar, and B. Taheri (2023). Adsorption of Gold and Silver Glycinate on Graphene and Graphene Oxide Surface: a DFT Study. Applied Surface Science, 619; 156676
Jabeen, S., A. S. Ganie, S. Hijazi, S. Bala, D. Bano, and T. Khan (2023). Fabrication and Studies of LaFe2O3/Sb2O3 Heterojunction for Enhanced Degradation of Malachite Green Dye Under Visible Light Irradiation. Inorganic Chemistry Communications, 152; 110729
Liu, Y., H. Guan, S. Lin, H. Dong, W. Hasi, and B. Dong (2022). Plasmonic Nanosensor Based on Ag Nanocubes of High Purification by Extraction Filtration Strategy for SERS Determination of Malachite Green in Aquaculture Water. Sensors and Actuators B: Chemical, 358; 131515
Modwi, A., A. Albadri, and K. K. Taha (2023). High Malachite Green Dye Removal by ZrO2-g-C3N4 (ZOCN) Meso-Sorbent: Characteristics and Adsorption Mechanism. Diamond and Related Materials; 109698
Mohadi, R., A. Amri, M. Badaruddin, N. Ahmad, and A. Lesbani (2023). Adsorption of Phenol from Aqueous Solution Using Zn/Al Layered Double Hydroxides-Cellulose Composite. Science and Technology Indonesia, 8(1); 123–128
Ni’mah, Y. L., A. P. K. Subandi, and S. Suprapto (2022). The Application of Silica Gel Synthesized from Chemical Bottle Waste for Zinc(II) Adsorption using Response Surface Methodology (RSM). Heliyon, 8(12); e11997
Palapa, N. R., T. Taher, S. Fajri, and A. Lesbani (2021). Adsorptive Removal of Malachite Green from Aqueous Solution over Graphite-Layered Double Hydroxides Composite. Chiang Mai Journal of Science, 48(5); 1351–1362
Rahman, N. and A. Raheem (2022). Graphene Oxide/Mg-Zn-Al Layered Double Hydroxide for Efficient Removal of Doxycycline from Water: Taguchi Approach for Optimization. Journal of Molecular Liquids, 354; 118899
Raval, A. R., H. P. Kohli, and O. K. Mahadwad (2022). Application of Emulsion Liquid Membrane for Removal of Malachite Green Dye from Aqueous Solution: Extraction and Stability Studies. Chemical Engineering Journal Advances, 12; 100398
Sabit, D. A. and S. E. Ebrahim (2023). Fabrication of Magnetic BiOBr/ZnFe2O4/CuO Heterojunction for Improving the Photocatalytic Destruction of Malachite Ggreen Ddye Under LED Irradiation: Dual S-Scheme Mechanism. Materials Science in
Semiconductor Processing, 163; 107559
Van Tran, T., D. T. C. Nguyen, P. S. Kumar, A. T. M. Din, A. S. Qazaq, and D. V. N. Vo (2022). Green Synthesis of Mn3O4 Nanoparticles using Costus woodsonii Flowers Extract for Effective Removal of Malachite Green Dye. Environmental Research, 214; 113925
Yang, W. and M. Cao (2022). Study on the Difference in aAdsorption Performance of Graphene Oxide and Carboxylated Graphene Oxide for Cu(II), Pb(II) Respectively and Mechanism Analysis. Diamond and Related Materials, 129; 109332
Yin, G., Z. Sun, Y. Gao, and S. Xu (2021). Preparation of Expanded Graphite for Malachite Green Dye Removal from Aqueous Solution. Microchemical Journal, 166; 106190
You, X., R. Zhou, Y. Zhu, D. Bu, and D. Cheng (2022). Adsorption of Dyes Methyl Violet and Malachite Green from Aqueous Solution on Multi-Step Modified Rice Husk Powder in Single and Binary Systems: Characterization, Adsorption Behavior and Physical Interpretations. Journal of Hazardous Materials, 430; 128445
Zhang, X., Z. Song, Y. Dou, Y. Xue, Y. Ji, Y. Tang, and M. Hu (2021). Removal Difference of Cr(VI) by Modified Zeolites Coated with MgAl and ZnAl-Layered Double Hydroxides: Efficiency, Factors and Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 621; 126583
