Rice Husks as Green Adsorbents for Removal of Anionic Dyes: Kinetic, Isotherm and Thermodynamic Adsorption Studies

Authors

  • Nur Ahmad Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Ogan Ilir, 30662, Indonesia
  • Neza Rahayu Palapa Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Ilir, 30662, Indonesia
  • Tarmizi Taher Department of Environmental Engineering, Institut Teknologi Sumatera, Jl. Terusan Ryacudu, Way Hui, Lampung Selatan, 35365, Indonesia

DOI:

https://doi.org/10.26554/ijmr.2023115

Keywords:

Green Adsorbent, Rice Husks, Procion Red, Adsorption

Abstract

Rice husk, a green adsorbent, was used for procion red adsorption. Analysis with BET, XRD, FTIR, and SEM confirmed the formation of rice husk. The results indicate that rice husk is more porous and has a rougher surface. The surface of the rice husk has a non-uniform shape and uneven morphology. The pore of rice husk is critical to the adsorption process of procion red. The procion red will enter the pore of the rice husk to make an interaction. The rice husk has a surface area, pore volume, and pore diameter of 7.08 m2/g, 0.011 cc/g, and 3.14 nm, respectively. The vibrational peak at 3448 1620, 1103, and 794 cm−1. the XRD powder patterns of rice husk characterization diffraction peak at 2θ 23°. Rice husk’s adsorption system for procion red removal follows PSO kinetic and Freundlich isotherm models with a maximal removal capacity of 158.730 mg/g. This study sheds light on the effectiveness of rice husk as an adsorbent for procion red contaminants.

References

Ahmad, N., F. S. Arsyad, I. Royani, and A. Lesbani (2023a). Charcoal Activated as Template Mg/Al Layered Double Hydroxide for Selective Adsorption of Direct Yellow on Anionic Dyes. Results in Chemistry, 5; 100766

Ahmad, N., F. S. Arsyad, I. Royani, P. M. S. B. N. Siregar, T. Taher, and A. Lesbani (2023b). High Regeneration of ZnAl/NiAl-Magnetite Humic Acid for Adsorption of Congo Red from Aqueous Solution. Inorganic Chemistry Communications, 150; 110517

Anuar, F., T. Hadibarata, M. Syafrudin, and Z. Fona (2020). Removal of Procion Red MX-5B from Aqueous Solution by Adsorption on Parkia speciosa (Stink Bean) Peel Powder. Biointerface Research in Applied Chemistry, 10; 4774–4779

Araichimani, P., K. Prabu, G. S. Kumar, G. Karunakaran, S. Surendhiran, M. Shkir, and H. E. Ali (2022). Synthesis of Fe3O4-Decorated SiO2 Nanostructure using Rice Husk as a Source by Microwave Combustion for the Development of a Magnetically Recoverable Adsorbent. Ceramics International, 48(7); 10339–10345

Bai, W., M. Qian, Q. Li, S. Atkinson, B. Tang, Y. Zhu, and J. Wang (2021). Rice Husk-Based Adsorbents for Removing Ammonia: Kinetics, Thermodynamics and Adsorption Mechanism. Journal of Environmental Chemical Engineering, 9(4); 105793

Chaari, I., A. Touil, and M. Medhioub (2021). Adsorption-Desorption of Phenolic Compounds from Olive Mills Wastewater using Tunisian Natural Clay. Chinese Journal of Chemical Engineering, 40; 287–292

Chaiyapongputti, P., P. Tooptompong, J. Setthayanond, and P. Munsuwan (2014). Development of Adsorbent Material from Tamarind-Seed Testa for Reactive Dye Adsorption. In Applied Mechanics and Materials, 535; 650–653

Chouaybi, I., H. Ouassif, M. Bettach, and E. M. Moujahid (2022). Fast and High Removal of Acid Red 97 Dye from Aqueous Solution by Adsorption Onto a Synthetic Hydrocalumite: Structural Characterization and Retention Mechanisms. Inorganic Chemistry Communications, 146; 110169

Dhaneswara, D., H. S. Marito, J. F. Fatriansyah, N. Sofyan, D. R. Adhika, and I. Suhariadi (2022). Spherical SBA-16 Particles Synthesized from Rice Husk Ash and Corn Cob Ash for Efficient Organic Dye Adsorbent. Journal of Cleaner Production, 357; 131974

Fahira, C. A., D. R. Damayanti, A. Febrianti, and R. A. Lestari (2021). Adsorb Red Procion in Batik Waste used Baggase Adsorbent. In AIP Conference Proceedings, 2349; 020069

Fraga, T. J. M., L. E. M. de Lima, Z. S. B. de Souza, M. N. Carvalho, E. M. P. d. L. Freire, M. G. Ghislandi, and M. A. da Motta (2019). Amino-Fe3O4-Functionalized Graphene Oxide as a Novel Adsorbent of Methylene Blue: Kinetics, Equilibrium, and Recyclability Aspects. Environmental Science and Pollution Research, 26; 28593–28602

Georgin, J., B. da Silva Marques, J. da Silveira Salla, E. L. Foletto, D. Allasia, and G. L. Dotto (2018). Removal of Procion Red Dye from Colored Effluents using H2SO4-/HNO3-Treated Avocado Shells (Persea americana) as Adsorbent. Environmental Science and Pollution Research, 25; 6429–6442

Ghibate, R., O. Senhaji, and R. Taouil (2021). Kinetic and Thermodynamic Approaches on Rhodamine B Adsorption Onto Pomegranate Peel. Case Studies in Chemical and Environmental Engineering, 3; 100078

Haider, J. B., M. I. Haque, M. Hoque, M. M. Hossen, M. Mottakin, M. A. Khaleque, M. Johir, J. L. Zhou, M. B. Ahmed, and M. Zargar (2022). Efficient Extraction of Silica from Openly Burned Rice Husk Ash as Adsorbent for Dye Removal. Journal of Cleaner Production, 380; 135121

Hasanah, M., N. Juleanti, A. Priambodo, F. S. Arsyad, A. Lesbani, and R. Mohadi (2022). Utilization of Rambutan Peel as a Potential Adsorbent for the Adsorption of Malachite Green, Procion Red, and Congo Red Dyes. Ecological Engineering & Environmental Technology, 23(3); 148–157

Heo, J. W., L. An, J. Chen, J. H. Bae, and Y. S. Kim (2022). Preparation of Amine-Functionalized Lignins for the Selective Adsorption of Methylene Blue and Congo Red. Chemosphere, 295; 133815

Liu, Y., Q. Liu, J. Li, H. H. Ngo, W. Guo, J. Hu, M.-t. Gao, Q. Wang, and Y. Hou (2018). Effect of Magnetic Powder on Membrane Fouling Mitigation and Microbial Community/Composition in Membrane Bioreactors (MBRs) for Municipal Wastewater Treatment. Bioresource Technology, 249; 377–385

Mohadi, R., Z. Hanafiah, H. Hermansyah, and H. Zulkifli (2017). Adsorption of Procion Red and Congo Red Dyes using Microalgae Spirulina sp. Science and Technology Indonesia, 2(4); 102-104

Naik, R. L., M. R. Kumar, and T. B. Narsaiah (2023). Removal of Heavy Metals (Cu & Ni) from Wastewater using Rice Husk and Orange Peel as Adsorbents. Materials Today: Proceedings, 72; 92–98

Nor, N. M., T. Hadibarata, Z. Yusop, and Z. M. Lazim (2015). Removal of Brilliant Green and Procionred Dyes from Aqueous Solutionby Adsorption using Selected Agricultural Wastes. Jurnal Teknologi, 74(11); 117–122

Nyika, J. and M. Dinka (2022). Activated Bamboo Charcoal in Water Treatment: A Mini-Review. Materials Today: Proceedings, 56; 1904–1907

Palapa, N. R., T. Taher, N. Juleanti, N. Normah, and A. Lesbani (2021). Biochar from Rice Husk as Efficient Biosorbent for Procion Red Removal from Aqueous Systems. Applied Environmental Research, 43(3); 79–91

Palapa, N. R., T. Taher, N. Normah, and A. Lesbani (2022). NiAl Layered Double Hydroxide/Rice Husk Composite for the Efficient Removal of Malachite Green. Indonesian Journal of Chemistry, 22(1); 142–156

Phan, K. A., D. Phihusut, and N. Tuntiwiwattanapun (2022). Preparation of Rice Husk Hydrochar as an Atrazine Adsorbent: Optimization, Characterization, and Adsorption Mechanisms. Journal of Environmental Chemical Engineering, 10(3); 107575

Shamsollahi, Z. and A. Partovinia (2019). Recent Advances on Pollutants Removal by Rice Husk as a Bio-Based Adsorbent: A Critical Review. Journal of Environmental Management, 246; 314–323

Siraorarnroj, S., N. Kaewtrakulchai, M. Fuji, and A. Eiad-ua (2022). High Performance Nanoporous Carbon from Mulberry Leaves (L.) Residues Via Microwave Treatment Assisted Hydrothermal-Carbonization for Methyl Orange Adsorption: Kinetic, Equilibrium and Thermodynamic Studies. Materialia, 21; 101288

Sriramoju, S. K., P. S. Dash, and S. Majumdar (2021). Meso-Porous Activated Carbon from Lignite Waste and its Application in Methylene Blue Adsorption and Coke Plant Effluent Treatment. Journal of Environmental Chemical Engineering, 9(1); 104784

Taher, T., A. Munandar, N. Mawaddah, M. S. Wisnubroto, P. M. S. B. N. Siregar, N. R. Palapa, A. Lesbani, and Y. G. Wibowo (2023). Synthesis and Characterization of Montmorillonite–Mixed Metal Oxide Composite and its Adsorption Performance for Anionic and Cationic Dyes Removal. Inorganic Chemistry Communications, 147; 110231

Vedula, S. S. and G. D. Yadav (2022). Wastewater Treatment Containing Methylene Blue Dye as Pollutant using Adsorption by Chitosan Lignin Membrane: Development of Membrane, Characterization and Kinetics of Adsorption. Journal of the Indian Chemical Society, 99(1); 100263

Yang, Y., T. M. P. Nguyen, H. T. Van, Q. T. Nguyen, T. H. Nguyen, T. B. L. Nguyen, D. Van Thanh, T. V. Nguyen, P. Q. Thang, and M. Yılmaz (2022). ZnO Nanoparticles Loaded Rice Husk Biochar as an Effective Adsorbent for Removing Reactive Red 24 from Aqueous Solution. Materials Science in Semiconductor Processing, 150; 106960

Yuliasari, N., A. Wijaya, R. Mohadi, E. Elfita, and A. Lesbani (2022). Photocatalytic Degradation of Malachite Green by Layered Double Hydroxide Based Composites. Bulletin of Chemical Reaction Engineering & Catalysis, 17(2); 240–249

Downloads

Published

2023-03-29

Issue

Section

Articles