Layered Double Hydroxide Zn/M3+ (M3+= Al and Cr) as Highly Efficient Adsorbent of Heavy Metal Pb(II)

Authors

  • Zaqiya Artha Zahara Magister Programme in Environment Management, Sriwijaya University, Palembang, South Sumatra, 30139, Indonesia
  • Luna Silaen Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, South Sumatra, 30139, Indonesia
  • Normah Normah Research Center of Inorganic Materials and Coordination Complexes, Faculty ofMathematics and Natural Sciences, Sriwijaya University, Palembang, South Sumatera, 30139, Indonesia
  • Novie Juleanti Research Center of Inorganic Materials and Coordination Complexes, Faculty ofMathematics and Natural Sciences, Sriwijaya University, Palembang, South Sumatera, 30139, Indonesia
  • Neza Rahayu Palapa Research Center of Inorganic Materials and Coordination Complexes, Faculty ofMathematics and Natural Sciences, Sriwijaya University, Palembang, South Sumatera, 30139, Indonesia

DOI:

https://doi.org/10.26554/ijmr.2023114

Keywords:

Layered Double Hydroxide, Pb(II), Adsorption

Abstract

Synthesis of Zn-Al and Zn-Cr LDHs in this research was successfully carried out. The sucsessfully results can be seen from the XRD characterization which displays diffraction angles at 10 and 60 which indicates the presence of layered structures and anions. FT-IR data displays the presence of nitrate groups at wavenumber 1381 cm−1. BET data shows surface area of Zn-Al and Zn-Cr at 1.965, 31.638 m2/g, corresponding. pHpzc determination of Zn-Al material gets a pH below pHpzc which is 6.2 while Zn-Cr is at pHpzc which is 7.6. Able of Zn (Al/Cr) as adsorbent to adsorp Pb(II) was investigated through several parameters such as kinetics, isotherms, thermodynamics. Kinetic Adsorption for Zn-Al inclined follow PSO, while Zn-Cr follow PFO. Isotherm parameter for Zn-Al and Zn-Cr is Freundlich with a maximum adsorption capacity 74.127 mg/L, and 27.027 mg/L. Thermodynamic process shows that Zn-Al and Zn-Cr LDHs take place in endothermic and spontaneously.

References

Agarwal, M. and K. Singh (2017). Heavy Metal Removal from Wastewater using Various Adsorbents: a Review. Journal of Water Reuse and Desalination, 7(4); 387–419

Aljamali, N. M., R. Khdur, and I. O. Alfatlawi (2021). Physical and Chemical Adsorption and its Applications. International Journal of Thermodynamics and Chemical Kinetics, 7; 1–8

Alsawy, T., E. Rashad, M. El-Qelish, and R. H. Mohammed (2022). A Comprehensive Review on the Chemical Regeneration of Biochar Adsorbent for Sustainable Wastewater Treatment. Npj Clean Water, 5(1); 29

Asiabi, H., Y. Yamini, M. Shamsayei, and E. Tahmasebi (2017). Highly Selective and Efficient Removal and Extraction of Heavy Metals by Layered Double Hydroxides Intercalated with the Diphenylamine-4-Sulfonate: a Comparative Study. Chemical Engineering Journal, 323; 212–223

Bai, S., M. Chu, L. Zhou, Z. Chang, C. Zhang, and B. Liu (2022). Removal of Heavy Metals from Aqueous Solutions by X-Type Zeolite Prepared from Combination of Oil Shale Ash and Coal Fly Ash. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 44(2); 5113–5123

Boukhalfa, N., M. Boutahala, and N. Djebri (2017). Synthesis and Characterization of ZnAl Layered Double Hydroxide and Organo-K10 Montmorillonite for the Removal of Diclofenac from Aqueous Solution. Adsorption Science & Technology, 35(1-2); 20–36

Chazanah, I. N. and A. B. D. Nandiyanto (2022). Literature of Waste Management (Sorting Of Organic and Inorganic Waste) Through Digital Media in Community. International Journal of Research and Applied Technology, 2(1); 114–123

Chen, W., J. Xing, Z. Lu, J. Wang, S. Yu, W. Yao, A. M. Asiri, K. A. Alamry, X. Wang, and S. Wang (2018). Citrate-Modified Mg–Al Layered Double Hydroxides for Efficient Removal of Lead from Water. Environmental Chemistry Letters, 16; 561–567

Dinari, M., M. M. Momeni, and Y. Ghayeb (2016). Photodegradation of Organic Dye by ZnCrLa Layered Double Hydroxide as Visible-Light Photocatalysts. Journal of Materials Science: Materials in Electronics, 27; 9861–9869

El-Baz, A. A. A., I. A. Hendy, A. M. Dohdoh, and M. I. Srour (2020). Adsorption Technique for Pollutants Removal; Current New Trends and Future Challenges–a Review. The Egyptian International Journal of Engineering Sciences and Technology, 32(Civil and Architectural Engineering); 1–24

Gomes, A., D. Cocke, D. Tran, and A. Baksi (2016). Layered Double Hydroxides in Energy Research: Advantages and Challenges. Energy Technology 2015: Carbon Dioxide Management and Other Technologies; 309–316

Hirata, N., K. Tadanaga, and M. Tatsumisago (2015). Photocatalytic O2 Evolution from Water Over Zn–Cr Layered Double Hydroxides Intercalated with Inorganic Anions. Materials Research Bulletin, 62; 1–4

Joseph, L., B. M. Jun, J. R. Flora, C. M. Park, and Y. Yoon (2019). Removal of Heavy Metals from Water Sources in the Developing World using Low-Cost Materials: a Review. Chemosphere, 229; 142–159

Juleanti, N., N. Normah, P. M. S. B. N. Siregar, A. Wijaya, N. R. Palapa, T. Taher, N. Hidayati, R. Mohadi, and A. Lesbani (2022). Comparison of the Adsorption Ability of MgAl-HC, CaAl-HC, and ZaAl-HC Composite Materials Based on Duku Peel Hydrochar in Adsorption of Direct Green Anionic Dyes. Indonesian Journal of Chemistry, 22(1); 192–204

Kajama, M., N. Nwogu, and E. Gobina (2015). Hydrogen Permeation using Nanostructured Silica Membranes. Sustain Dev Plan VII, 193; 447–456

Kalam, S., S. A. Abu-Khamsin, M. S. Kamal, and S. Patil (2021). Surfactant Adsorption Isotherms: a Review. ACS Omega, 6(48); 32342–32348 Kaur, K. and R. Jindal (2018). Synergistic Effect of Organic-Inorganic Hybrid Nanocomposite Ion Exchanger on Photocatalytic Degradation of Rhodamine-B Dye and Heavy Metal Ion Removal from Industrial Effluents. Journal of Environmental Chemical Engineering, 6(6); 7091–7101

Lesbani, A. L., N. Normah, N. R. Palapa, T. Taher, R. Andreas, and R. Mohadi (2020). Removal of Iron(II) using Ni/Al Layered Double Hydroxide Intercalated with Keggin Ion. Molekul, 15(3); 149–157

Liu, W., Y. Liu, Z. Yuan, and C. Lu (2023). Recent Advances in the Detection and Removal of Heavy Metal Ions using Functionalized Layered Double Hydroxides: a Review. Industrial Chemistry & Materials, 1(1); 79–92

Min, K. J., J. H. Kim, and K. Y. Park (2021). Characteristics of Heavy Metal Separation and Determination of Limiting Current Density in a Pilot-Scale Electrodialysis Process for Plating Wastewater Treatment. Science of the Total Environment, 757; 143762

Mohadi, R., P. M. S. B. N. Siregar, N. R. Palapa, and A. Lesbani (2022). Preparation of Zn/Al Chitosan Composite for the Selective Adsorption of Methylene Blue Dye in Water. Makara Journal of Science, 26(2); 128–136

Moussa, D. T., M. H. El-Naas, M. Nasser, and M. J. Al-Marri (2017). A Comprehensive Review of Electrocoagulation for Water Treatment: Potentials and Challenges. Journal of Environmental Management, 186; 24–41

Nag, R. and E. Cummins (2022). Human Health Risk Assessment of Lead (Pb) Through the Environmental-Food Pathway. Science of the Total Environment, 810; 151168

Oktriyanti, M., N. R. Palapa, R. Mohadi, and A. Lesbani (2020). Effective Removal of Iron(II) from Aqueous Solution by Adsorption using Zn/Cr Layered Double Hydroxides Intercalated with Keggin Ion. Journal of Ecological Engineering, 21(5); 63–71

Palapa, N. R., P. M. S. B. N. Siregar, A. Wijaya, T. Taher, and A. Lesbani (2022). High Selectivity and Stability Structure of Layered Double Hydroxide-Biochar for Removal Cd(II). Bulletin of Chemical Reaction Engineering & Catalysis, 17(3); 520–532

Qasem, N. A., R. H. Mohammed, and D. U. Lawal (2021). Removal of Heavy Metal Ions from Wastewater: a Comprehensive and Critical Review. Npj Clean Water, 4(1); 36

Raj, K. and A. P. Das (2023). Lead Pollution: Impact on Environment and Human Health and Approach for a Sustainable Solution. Environmental Chemistry and Ecotoxicology, 5; 79–85

Rojas, R. (2014). Copper, Lead and Cadmium Removal by Ca Al Layered Double Hydroxides. Applied Clay Science, 87; 254–259

Samaei, S. M., S. Gato-Trinidad, and A. Altaee (2020). Performance Evaluation of Reverse Osmosis Process in the Post-Treatment of Mining Wastewaters: Case Study of Costerfield Mining Operations, Victoria, Australia. Journal of Water Process Engineering, 34; 101116

Silaen, L., R. Mohadi, N. Juleanti, N. R. Palapa, and A. Lesbani (2021). Soft Ion Divalent Metals Toward Adsorption on Zn/AlPOM Layered Double Hydroxide. Journal of Ecological Engineering, 22(10); 109–120

Tang, L., X. Xie, C. Li, Y. Xu, W. Zhu, and L. Wang (2022). Regulation of Structure and Anion Exchange Performance of Layered Double Hydroxide: Function of the Metal Cation Composition of a Brucite-like Layer. Materials, 15(22); 7983

Wang, Z., L. Zhang, P. Fang, L. Wang, and W. Wang (2020). Study on Simultaneous Removal of Dye and Heavy Metal Ions by NiAl-Layered Double Hydroxide Films. ACS Omega, 5(34); 21805–21814

Zhang, S., N. Kano, and H. Imaizumi (2016). Adsorption of Cd

(II) on Zn-Al LDHs (Layered Double Hydroxides) Intercalated

with Chelating Agents EDTA. Journal of Chemistry and Chemical Engineering, 10(2); 60–67

Zhu, X. K., J. Benefield, T. B. Coplen, Z. Gao, and N. E. Holden

(2021). Variation of Lead Isotopic Composition and Atomic

Weight in Terrestrial Materials (IUPAC Technical Report). Pure

and Applied Chemistry, 93(1); 155–166

Downloads

Published

2023-03-29

Issue

Vol. 1 No. 1 (2023): March

Section

Articles