Intercalation and Structural Reconstruction of Ca/Al Layered Double Hydroxides

Authors

  • Danang Abriyanto Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia
  • Novie Juleanti Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia
  • Normah Normah Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia
  • Aldes Lesbani Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia

DOI:

https://doi.org/10.26554/ijmr.20242234

Keywords:

Intercalation, Layered Double Hydroxides (LDH), Ca/Al, Reconstruction

Abstract

The intercalation of of Ca/Al layered double hydroxide (LDH) has been successfully conducted into using several intercalants with different size compounds after termal treatment process to reconstruct structure of Ca/Al LDH. Ca/Al LDH was synthesized by co-precipitation at pH 11 then calcination at various temperatures following with intercalation using water, sodium hydroxide, sodium carbonate and Keggin type of polyoxometalate K4[α-SiW12O40]. Characterization of Ca/Al LDH was carried out by XRD and FTIR analyses. XRD analysis showed that unique diffraction peak of Ca/Al LDH at 10o with interlayer space 4.67 Å. Gradual thermal treatment of Ca/Al LDH was achieved until loss unique diffraction peak at temperature 700 oC to form shrinking layer. Intercalation of water, sodium hydroxide, sodium carbonate, and polyoxometalate to shrink layer of Ca/Al LDH can create formation of well crystalline LDH to reconstruct layer structure with formation of unique diffraction at 10◦. The interlayer distance of Ca/Al LDH was increased after intercalation process. Thus reconstruction structure of LDH was successfully conducted with flexibility of layer.

References

Barkhordari, S. and M. Yadollahi (2016). Carboxymethyl Cellulose Capsulated Layered Double Hydroxides/Drug Nanohybrids for Cephalexin Oral Delivery. Applied Clay Science, 121-122; 77–85

Belin, T., C. Mve Mfoumou, S. Mignard, and Y. Pouilloux (2013). Study of Physisorbed Carbon Dioxide on Zeolites Modified by Addition of Oxides or Acetate Impregnation. Microporous and Mesoporous Materials, 182; 109–116

Carriazo, D., S. Lima, C. Martín, M. Pillinger, A. A. Valente, and V. Rives (2007). Metatungstate and Tungstoniobate-Containing LDHs: Preparation, Characterisation and Activity in Epoxidation of Cyclooctene. Journal of Physics and Chemistry of Solids, 68(10); 1872–1880

Duan, X., J. Lu, and D. G. Evans (2011). Assembly Chemistry of Anion-Intercalated Layered Materials. Elsevier B.V.

Fitri, E. S., T. N. Yunita, R. Mohadi, and A. Lesbani (2023). Ca/Al and Mg/Al LDH Supported on Biochars As Effective Adsorbent and Highly Regeneration Ability for Phenol Removal from Aqueous Solution. Indonesian Journal of Material Research, 1(3); 106–116

Granados-Reyes, J., P. Salagre, and Y. Cesteros (2017). Effect of the Preparation Conditions on the Catalytic Activity of Calcined Ca/Al-Layered Double Hydroxides for the Synthesis of Glycerol Carbonate. Applied Catalysis A: General, 536; 9–17

Gómez-Avilés, A., P. Aranda, and E. Ruiz-Hitzky (2016). Layered Double Hydroxide/Sepiolite Heterostructured Materials. Applied Clay Science, 130; 83–92

Hanifah, Y. and N. R. Palapa (2016). Mg/Al Layered Double Hydroxide: Intercalation with H3[α PW12O40]•nH2O. Science and Technology Indonesia, 1; 16–19

Hasannia, S. and B. Yadollahi (2015). Zn-Al LDH Nanostructures Pillared by Fe Substituted Keggin Type Polyoxometalate: Synthesis, Characterization and Catalytic Effect in Green Oxidation of Alcohols. Polyhedron, 99(3); 260–265

Huang, J., L. Valenzano, and G. Sant (2015). Framework and Channel Modifications in Mayenite (12CaO·7Al2O3) Nanocages by Cationic Doping. Chemistry of Materials, 27(13); 4731–4741

Jia, Y., Y. Zhang, J. Fu, L. Yuan, Z. Li, C. Liu, D. Zhao, and X. Wang (2019). A Novel Magnetic Biochar / MgFe-Layered Double Hydroxides Composite Removing Pb2+ From Aqueous Solution: Isotherms, Kinetics and Thermodynamics. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 567(January); 278–287

Lesbani, A., A. Marpaung, M. Verawaty, H. Rizki Amalia, and R. Mohadi (2016). Catalytic Desulfurization of Benzothiophene Using Keggin Type Polyoxometalates as Catalyst. Journal of Pure and Applied Chemistry Research, 4(1); 5–11

Lesbani, A., T. Taher, N. R. Palapa, R. Mohadi, A. Rachmat, and Mardiyanto (2020). Preparation and Utilization of Keggin-Type Polyoxometalate Intercalated Ni-Fe Layered Double Hydroxides for Enhanced Adsorptive Removal of Cationic Dye. SN Applied Sciences, 2; 470

Ma, S., C. Fan, L. Du, G. Huang, X. Yang, W. Tang, Y. Makita, and K. Ooi (2009). Intercalation of Macrocyclic Crown Ether into Well-Crystallized LDH: Formation of Staging Structure and Secondary Host-Guest Reaction. Chemistry of Materials, 21(15); 3602–3610

Mishra, G., B. Dash, and S. Pandey (2018). Layered Double Hydroxides: A Brief Review from Fundamentals to Application as Evolving Biomaterials. Applied Clay Science, 153(October 2017); 172–186

Omwoma, S., W. Chen, R. Tsunashima, and Y. F. Song (2014). Recent Advances on Polyoxometalates Intercalated Layered Double Hydroxides: From Synthetic Approaches to Functional Material Applications. Coordination Chemistry Reviews, 258-259(1); 58–71

Qu, J., L. Zhong, Z. Li, M. Chen, Q. Zhang, and X. Liu (2016). Effect of Anion Addition on the Syntheses of Ca Al Layered Double Hydroxide via a Two-Step Mechanochemical Process. Applied Clay Science, 124-125; 267–270

Ramanathan, G., L. S. Liji, P. Fardim, and U. T. Sivagnanam (2018). Fabrication of 3D Dual-Layered Nanofibrous Graft Loaded with Layered Double Hydroxides and Their Effects in Osteoblastic Behavior for Bone Tissue Engineering. Process Biochemistry, 64(September); 255–259

Starukh, H. and S. Levytska (2019). The Simultaneous Anionic and Cationic Dyes Removal with Zn-Al Layered Double Hydroxides. Applied Clay Science, 180(June); 0–5

Tran, H. N., C. C. Lin, and H. P. Chao (2018). Amino Acids-Intercalated Mg/Al Layered Double Hydroxides as Dual-Electronic Adsorbent for Effective Removal of Cationic and Oxyanionic Metal Ions. Separation and Purification Technology, 192; 36–45

Woo, M. A., T. Woo Kim, M. J. Paek, H. W. Ha, J. H. Choy, and S. J. Hwang (2011). Phosphate-Intercalated CaFe-Layered Double Hydroxides: Crystal Structure, Bonding Character, and Release Kinetics of Phosphate. Journal of Solid State Chemistry, 184(1); 171–176

Wu, Y., X. Liu, Y. Lei, Y. Qiu, M. Wang, and H. Wang (2017). Synthesis and Characterization of 12-Tungstophosphoric Acid Intercalated Layered Double Hydroxides and Their Application as Esterification Catalysts for Deacidification of Crude Oil. Applied Clay Science, 150(April); 34–41

Zahra Mahjoubi, F., A. Khalidi, A. Elhalil, R. Elmoubarki, O. Cherkaoui, S. Mhamed, and N. Barka (2017). Performance of Zn-, Mg-and Ni-Al layered double hydroxides in treating an industrial textile wastewater. Journal of Applied Surfaces and Interfaces, 2(1-3); 1–11

Zhang, J., D. Xu, W. Qian, J. Zhu, and F. Yan (2016). Host-Guest Inclusion Complexes Derived Heteroatom-Doped Porous Carbon Materials. Carbon, 105; 183–190

Zhu, J., J. He, X. Du, R. Lu, L. Huang, and X. Ge (2011). A Facile and Flexible Process of β-Cyclodextrin Grafted on Fe3O4 Magnetic Nanoparticles and Host-Guest Inclusion Studies. Applied Surface Science, 257(21); 9056–9062

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Published

2024-07-26

Issue

Vol. 2 No. 2 (2024): July

Section

Articles