Abstract
Water pollution due to synthetic dye waste is a serious environmental problem, so an effective method is needed to overcome it, including using adsorption. In this study, Ni/Al-Cs materials were synthesized and characterized to evaluate their selectivity towards Rhodamine B (RhB), Malachite Green (MG), and Methylene Blue (MB) dyes. Adsorption selectivity tests were conducted using UV-Vis spectroscopy to determine changes in dye concentration before and after interaction with the material. Results showed that Ni/Al-Cs had the highest adsorption capacity towards MG, followed by MB and RhB. With its selective adsorption properties, Ni/Al-Cs material has the potential to be used as an effective adsorbent in the treatment of dye effluents in aquatic environments, especially MG dye.
Keywords
References
- Ahmad, N., A. R. Marlan, and S. P. J. Negara (2024a). Insight of Anionic Dyes Adsorption from Their Aqueous Solutions onto MgAl. Indonesian Journal of Material Research, 2(2); 40–46.
- Ahmad, N., A. Wijaya, F. S. Arsyad, I. Royani, and A. Lesbani (2024b). Layered Double Hydroxide-Functionalized Humic Acid and Magnetite by Hydrothermal Synthesis for Optimized Adsorption of Malachite Green. Kuwait Journal of Science, 51(2); 100206.
- Gao, X., X. W. Han, J. Sun, S. Wang, C. Lu, and H. Zou (2025). (MgFe) LDHs Decorated 3D Reduced Graphene Oxide Nanocomposite for Adsorption of Ciprofloxacin and Norfloxacin. Diamond and Related Materials, 153; 112085.
- Huang, A., N. Zhang, Q.-B. Wang, B.-H. Zhao, R.-B. Zhang, M. Cheng, C. Shi, and X.-D. Hao (2025). Enhanced Wastewater Treatment Using Biochar-Supported Layered-Double Hydroxide Composites. Chemical Engineering Journal, 506; 159969.
- Jamshidi, E., F. Fathabadi, F. Manteghi, and R. Eshaghimalekshah (2025). Adsorption Characteristics of Metronidazole on CoZr LDH and Its GO Nanocomposite: Experimental and Theoretical Study. Heliyon, 11(3); e42396.
- Khlyustova, A., N. Sirotkin, M. Shipko, Z. Kalazhokov, H. Kalazhokov, M. Stepovich, E. Savchenko, and A. Agafonov (2025). Plasma Chemical Synthesis of Magnetic Fe₂O₃-Cr Layered Double Hydroxide Composites for Environmental Applications. Solid State Communications, 399; 115886.
- Li, X., Z. Huang, B. Wan, L. Yang, Z. Chen, S. Zhang, X. Liu, C. Cheng, Y. Zhu, C. Lu, J. Zou, L. Chen, and S. Luo (2025). Oxygen Vacancy-Enriching Co₃O₄/FeNi LDH Boosts Rapid Degradation of Formaldehyde Under Natural Light at Room Temperature. Separation and Purification Technology, 362; 131964.
- Liu, N., T.-B. Fang, L.-X. Zhao, N. Li, X.-F. Chen, and R.-S. Zhao (2025). Efficient Adsorption Behavior of Fe-Based Ternary Magnetic LDHs for Naphthalene Acetic Acid: Role of Fe Element. Environmental Research, 269; 120848.
- Loto, C. A., O. O. Joseph, and R. T. Loto (2014). Adsorption and Inhibitive Properties of Camellia Sinensis for Aluminium Alloy in HCl. International Journal of Electrochemical Science, 9(7); 3637–3649.
- Luo, Y., Y. Wang, F. Hua, M. Xue, X. Xie, Y. Xie, S. Yu, L. Zhang, Z. Yin, C. Xie, and Z. Hong (2023). Adsorption and Photodegradation of Reactive Red 120 with Nickel-Iron-Layered Double Hydroxide/Biochar Composites. Journal of Hazardous Materials, 443(PB); 130300.
- Ma, Y., Q. Luo, J. Li, X. Wang, F. Ma, M. Li, X. Ye, K. Li, X. Du, X. Wang, and Z. Wu (2024). One-Pot Synthesis of Transition Metals-Doped LiAl LDHs to Improve Lithium Adsorption Performance and Stability. Process Safety and Environmental Protection, 192; 878–886.
- Mansour, E. A., M. Taha, R. K. Mahmoud, N. Shehata, and R. M. Abdelhameed (2025). A Combined Experimental and Computational Studies on Thiophene Adsorption from Liquid Fuels over ZIF-67@ZnFe LDH Composites. Materials Chemistry and Physics, 334; 130499.
- Oktriyanti, M., N. R. Palapa, R. Mohadi, and A. Lesbani (2019). Modification of ZnCr Layered Double Hydroxide with Keggin Ion. Indonesian Journal of Environmental Management and Sustainability, 3(3); 93–99.
- Rakcho, Y., M. Baidou, A. Naboulsi, A. Bouazizi, M. Mouiya, H. Sehaqui, Y. Abouliatim, A. Benhammou, M. Ouammou, A. Abourriche, and J. Alami (2025). Fabrication of Low-Cost Ceramic Nanofiltration Membrane from Natural Resources for the Removal of Cationic and Anionic Dyes: Experimental and DFT Investigations. Chemical Engineering Journal, 505; 159779.
- Rohmatullaili, N. Ahmad, D. Erviana, Zultriana, D. Savira, R. Mohadi, and A. Lesbani (2024). ZnAlLDH-Based Derivative Materials as Photocatalysts: Synthesis, Characterization, and Catalytic Performance in Tetracycline Degradation. Science and Technology Indonesia, 9(2); 457–469.
- Sowmya, P. and A. Joseph (2025). Effective Removal of Cationic Dyes in a Single Aliquot Using Thiophene-Based Bis-Chalcone Polymers. Reactive and Functional Polymers, 210; 106189.
- Tamang, R., A. K. Mehata, V. Singh, M. S. Muthu, and B. Koch (2025). Sustainable Synthesis of Camellia Sinensis-Mediated Silver Nanoparticles (CsAgNP) and Their Anticancer Mechanisms in Breast Cancer Cells. Biomaterials Advances, 166; 214072.
- Tamura, K., J. Tanks, D. Niizeki, Y. Watanabe, T. Kogure, H. Sakuma, and M. Kamon (2025). Heavy Metal Ion Adsorption Mechanism of Polysulfide-Modified Layered Double Hydroxide. Applied Clay Science, 269; 107759.
- Wang, X., H. Li, X. Li, J. Wu, Z. Pang, Z. Ji, and S. Wang (2025). Separation of Ethylparaben Using Cellulose Nanocrystals/MgAl Layered Double Hydroxides Composite Films and Mechanistic Investigation. Journal of Environmental Chemical Engineering, 13(1); 115157.
- Wen, C., Y. Huang, W. Zhang, J. Tian, C. Dong, C. Yang, and W. Liang (2025). Efficient and Convenient Purification Strategy Using Maltodextrin-Based Nanosponges for Rapid Removal of Cationic Dyes. Separation and Purification Technology, 362; 131702.
- Wijaya, A., R. Ardiansyah, E. Augustiara, and S. Fajri (2024). Preparation of Hydrochar from Longan Peel: A Promising Adsorbent for Cationic Dye Removal in Aqueous Solutions. Indonesian Journal of Material Research, 2(3); 79–85.
- Xu, T., C. Fei, H. Zhou, Y. Fan, K. Tang, C. Chen, D. Ju, Z. Zhu, and R. Mao (2025). The Formation and Adsorption Mechanism Studies of Three-Dimensional (3D Flower-Like) Layered Double Hydroxide. Applied Surface Science, 691; 162671.
- Yilmaz, P., D. Gunduz, and B. Ozbek (2021). Utilization of Low-Cost Bio-Waste Adsorbent for Methylene Blue Dye Removal from Aqueous Solutions and Optimization of Process Variables by Response Surface Methodology Approach. Desalination and Water Treatment, 224; 367–388.