Enhanced Selectivity of Ni/Al LDH for Cationic Dye Adsorption via Gambier Leaf Extract Modification

Authors

  • Jefri Jefri Master Program of Material Science, Graduate School, Universitas Sriwijaya, Palembang, 30139, Indonesia
  • Najma Annuria Fithri Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Iliri, 30862, Indonesia
  • Navinda Ramadhan Master Program of Material Science, Graduate School, Universitas Sriwijaya, Palembang, 30139, Indonesia

DOI:

https://doi.org/10.26554/ijmr.20253148

Keywords:

Selectivity, Adsorption, Ni/Al LDH, Gambier Leaf Extract, Cationic Dyes

Abstract

The adsorption capability of Ni/Al LDH modified with gambier leaf extract was evaluated for the removal of Rhodamine B (RhB), Malachite Green (MG), and Methylene Blue (MB) dyes from aqueous solutions. UV-Vis spectroscopy analysis revealed that Ni/Al-Gambier Leaf Extract exhibited a higher efficiency in cationic dye removal compared to unmodified Ni/Al LDH. The removal percentages of RhB, MG, and MB using unmodified Ni/Al LDH were 6.00%, 40.05%, and 14.73%, respectively. However, after modification with Gambier Leaf Extract, these values significantly improved to 25.62%, 39.48%, and 31.06%, respectively. This enhancement was attributed to the polyphenolic functional groups present in the gambier leaf extract, which strengthened electrostatic interactions and promoted dye adsorption. These findings indicate that incorporating gambier leaf extract into Ni/Al LDH enhances its adsorption performance, making it a promising material for improving dye removal in wastewater treatment.

References

Abbas, M. and M. Trari (2023). Contribution of Zeolite to Remove Malachite Green in Aqueous Solution by Adsorption Processes: Kinetics, Isotherms and Thermodynamic Studies. Textile Research Journal, 93(15–16); 3765–3776.

Abd El-Monaem, E. M., H. M. Elshishini, S. S. Bakr, H. G. ElAqapa, M. Hosny, G. Andaluri, G. M. El-Subruiti, A. M. Omer, and A. S. Eltaweil (2023). A Comprehensive Review on LDH-Based Catalysts to Activate Persulfates for the Degradation of Organic Pollutants. npj Clean Water, 6(34); 1–24.

Abdel-Hady, E. E., S. H. M. Hafez, H. F. M. Mohamed, and M. R. M. Elsharkawy (2024). Characterization and Application of LDH with Chitosan Composites Investigated by Positron Annihilation Lifetime Spectroscopy and Surface Texture for the Adsorption of Methyl Orange. Scientific Reports, 14(1); 16501.

Abdelrahman, A. A., S. H. Bendary, and S. A. Mahmoud (2023). Synthesis and Electrochemical Properties of NiAl LDH@RGO Hierarchical Nanocomposite as a Potential Counter Electrode in Dye Sensitized Solar Cells. Diamond and Related Materials, 134; 109738.

Ahmad, N., F. S. Arsyad, I. Royani, Y. Hanifah, and A. Lesbani (2025). Lignin-NiAl Layered Double Hydroxide Composite Adsorbent for Selective Removal of Malachite Green from Aqueous Solutions of Cationic Dyes. Chemistry Africa; 1–11.

Ahmad, N., A. R. Marlan, and S. P. J. Negara (2024a). Insight of Anionic Dyes Adsorption from Their Aqueous Solutions onto MgAl LDH/Lignin: Characterization and Isotherm Studies. Indonesian Journal of Material Research, 2(2); 40–46.

Ahmad, N., Rohmatullaili, A. Wijaya, and A. Lesbani (2024b). Magnetite Humic Acid-Decorated MgAl Layered Double Hydroxide and Its Application in Procion Red Adsorption. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 684; 133042.

Al-Tohamy, R., S. S. Ali, F. Li, K. M. Okasha, Y. A. G. Mahmoud, T. Elsamahy, H. Jiao, Y. Fu, and J. Sun (2022). A Critical Review on the Treatment of Dye-Containing Wastewater: Ecotoxicological and Health Concerns of Textile Dyes and Possible Remediation Approaches for Environmental Safety. Ecotoxicology and Environmental Safety, 231; 113160.

Alsukaibi, A. K. D. (2022). Various Approaches for the Detoxification of Toxic Dyes in Wastewater. Processes, 10(10); 1968.

Azanaw, A., B. Birlie, B. Teshome, and M. Jemberie (2022). Textile Effluent Treatment Methods and Eco-Friendly Resolution of Textile Wastewater. Case Studies in Chemical and Environmental Engineering, 6; 100230.

Bessaha, F., G. Bessaha, S. Ziane, and A. Khelifa (2023). Adsorption of Methyl Orange on Bentonite: Design, Modeling, and Analysis of Experiments. Iranian Journal of Chemistry and Chemical Engineering, 42(10); 3306–3323.

Bezerra, B. G. P., L. Bieseki, D. R. da Silva, and S. B. C. Pergher (2019). Development of a Zeolite A/LDH Composite for Simultaneous Cation and Anion Removal. Materials, 12; 661.

Du, C., T. Hu, C. Tang, Y. Liu, J. Deng, S. Wang, S. Yan, and X. Hu (2024). Rapid Removal of Rhodamine B by Phosphoric Acid-Modified Activated Carbon Derived from Rape Straw. Environmental Technology, 45(27); 5855–5864.

Foruzin, L. J., F. Nasirpouri, and H. Dai (2025). Electrochemically-Deposited NiAl-Layered Double Hydroxide/Ni Electrocatalysts for Enhanced Magnetic Water Oxidation. Applied Clay Science, 269; 107770.

Fukumori, Y., H. Takeuchi, and Y. Ando (2018). Structural Control of Nanoparticles. In Nanoparticle Technology Handbook. pages 49–107.

Hanifah, Y., R. Mohadi, M. Mardiyanto, and A. Lesbani (2022). Photocatalytic Degradation of Malachite Green by NiAl-LDH Intercalated Polyoxometalate Compound. Bulletin of Chemical Reaction Engineering and Catalysis, 17(3); 627–637.

Hu, X., W. Zheng, M. Wu, L. Chen, and S. Chen (2023). Composites of Metal-Organic Frameworks (MOFs) and LDHs for Energy Storage and Environmental Applications: Fundamentals, Progress, and Perspectives. Sustainable Materials and Technologies, 37; e00691.

Intachai, S., P. Pimchan, and P. Sumanatrakul (2019). Synthesis of NiAl-Layered Double Oxide as Inorganic Adsorbent for Eliminating Dye from Solution. Naresuan University Journal: Science and Technology, 27(4); 66–74.

Jagadeesh, N. and B. Sundaram (2023). Adsorption of Pollutants from Wastewater by Biochar: A Review. Journal of Hazardous Materials Advances, 9; 100226.

Jefri, J., N. A. Fithri, and A. Lesbani (2024). Enhanced Removal Efficiency of Malachite Green Dye Using Gambir Leaf Extract-Modified NiFe LDH Composites: A Study of Cationic Dye Adsorption. Bulletin of Chemical Reaction Engineering & Catalysis, 19(4); 573–584.

Kumari, U. (2024). Textile Dyes and Their Impact on the Natural Environment. In P. Singh, editor, Dye Pollution from Textile Industry: Challenges and Opportunities for Sustainable Development. Springer Nature Singapore, pages 17–30.

Lee, H., S. Fiore, and F. Berruti (2024). Adsorption of Methyl Orange and Methylene Blue on Activated Biocarbon Derived from Birchwood Pellets. Biomass and Bioenergy, 191; 107446.

Lesbani, A., N. Ahmad, R. Mohadi, I. Royani, S. Wibiyan, Amri, and Y. Hanifah (2024). Selective Adsorption of Cationic Dyes by Layered Double Hydroxide with Assist Algae (Spirulina platensis) to Enrich Functional Groups. JCIS Open, 15; 100118.

Lesbani, A., N. R. Palapa, R. J. Sayeri, T. Taher, and N. Hidayati (2021). High Reusability of NiAl LDH/Biochar Composite in the Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2); 421–434.

Lin, Y. R., Y. F. Hu, C. Y. Huang, H. T. Huang, Z. H. Liao, A. T. Lee, Y. S. Wu, and F. H. Nan (2022). Removing Malachite Green and Leucomalachite Green From Freshwater and Seawater With Four Water Treatment Agents. Frontiers in Environmental Science, 10; 906886.

Lu, Y., X. Li, X. Jing, Y. Huang, Y. Qiang, G. Cao, R. Qin, Q. Cao, J. Cao, and S. C. Lee (2024). Applications of Layered Double Hydroxide Nanomaterials in Environmental Remediation: Synthesis, Structural Modification and Performance Enhancement. Surfaces and Interfaces, 52; 104902.

Luo, Y., Y. Han, Y. Hua, M. Xue, S. Yu, L. Zhang, Z. Yin, X. Li, X. Ma, H. Wu, T. Liu, Y. Shen, and B. Gao (2022). Step Scheme Nickel-Aluminium Layered Double Hydroxides/Biochar Heterostructure Photocatalyst for Synergistic Adsorption and Photodegradation of Tetracycline. Chemosphere, 309; 136802.

Milos, E., L. Cocheci, A. Popa, L. Lupa, and A. Filimon (2024). Hybrid Materials Mg3Al LDH/Ionic Liquids/Chitosan Used in the Recovery Process of Pd Ions from Aqueous Solutions. Molecules, 29(24).

Mohadi, R., Normah, N. R. Palapa, and A. Lesbani (2022). M2+(Ni, Cu, Zn)/Al-LDH Composites with Hydrochar from Rambutan Peel and Study the Adsorption Efficiency for Organic Dyes. Environment and Natural Resources Journal, 20(2); 221–233.

Mohammadi, A. A., S. Moghanlo, M. S. Kazemi, S. Nazari, S. K. Ghadiri, H. N. Saleh, and M. Sillanpää (2022). Comparative Removal of Hazardous Cationic Dyes by MOF-5 and Modified Graphene Oxide. Scientific Reports, 12(1); 15314.

Nizam, N. U. M., M. M. Hanafiah, E. Mahmoudi, A. A. Halim, and A. W. Mohammad (2021). The Removal of Anionic and Cationic Dyes from an Aqueous Solution Using Biomass-Based Activated Carbon. Scientific Reports, 11(1); 1–17.

Oladoye, P. O., T. O. Ajiboye, E. O. Omotola, and O. J. Oyewola (2022). Methylene Blue Dye: Toxicity and Potential Elimination Technology from Wastewater. Results in Engineering, 16; 100678.

Potgieter, J., F. B. Waanders, and E. Fosso-Kankeu (2019). Removal of Malachite Green and Toluidine Blue Dyes from Aqueous Solution Using a Clay-Biochar Composite of Bentonite and Sweet Sorghum Bagasse. International Journal of Applied Engineering Research, 14(6); 1324–1333.

Priya, P. S., P. Pratiksha Nandhini, S. Vaishnavi, V. Pavithra, M. H. Almutairi, B. O. Almutairi, S. Arokiyaraj, R. Pachaiappan, and J. Arockiaraj (2024). Rhodamine B, an Organic Environmental Pollutant Induces Reproductive Toxicity in Parental and Teratogenicity in F1 Generation in Vivo. Comparative Biochemistry and Physiology Part C: Toxicology & Pharmacology, 280; 109898.

Rahayu Palapa, N., T. Taher, R. Mohadi, H. Paluta Utami, and A. Lesbani (2021). The Ability of Composite Ni/Al-Carbon Based Material Toward Readsorption of Iron(II) in Aqueous Solution. Science and Technology Indonesia, 6(3); 156–165.

Sadegh, N., H. Haddadi, F. Sadegh, and A. Asfaram (2022). Recent Advances and Perspectives of Tannin-Based Adsorbents for Wastewater Pollutants Elimination: A Review. Environmental Nanotechnology, Monitoring & Management, 19; 100763.

Santhi, T., S. Manonmani, V. S. Vasantha, and Y. T. Chang (2016). A New Alternative Adsorbent for the Removal of Cationic Dyes from Aqueous Solution. Arabian Journal of Chemistry, 9; S466–S474.

Septiningrum, F., A. H. Yuwono, F. A. Maulana, E. Nurhidayah, D. Dhaneswara, N. Sofyan, H. Hermansyah, and W. W. Purwanto (2024). Mangosteen Pericarp Extract Mediated Synthesis of Ag/TiO2 Nanocomposite and Its Application on Organic Pollutant Degradation by Adsorption-Photocatalytic Activity. Current Research in Green and Sustainable Chemistry, 8; 100394.

Sharma, J., S. Sharma, and V. Soni (2023). Toxicity of Malachite Green on Plants and Its Phytoremediation: A Review. Regional Studies in Marine Science, 62; 102911.

Singha Roy, A., S. Kesavan Pillai, and S. S. Ray (2023). A Comparison of Nitrate Release from Zn/Al-, Mg/Al-, and Mg–Zn/Al Layered Double Hydroxides and Composite Beads: Utilization as Slow-Release Fertilizers. ACS Omega, 8(9); 8427–8440.

Slama, H. B., A. Chenari Bouket, Z. Pourhassan, F. N. Alenezi, A. Silini, H. Cherif-Silini, T. Oszako, L. Luptakova, P. Golińska, and L. Belbahri (2021). Diversity of Synthetic Dyes from Textile Industries, Discharge Impacts and Treatment Methods. Applied Sciences, 11(14); 6255.

Wahyuningsih, S., V. Anjani, H. Munawaroh, and C. Purnawan (2018). Optimization of Rhodamine B Decolorization by Adsorption and Photoelectrodegradation Combination System. ALCHEMY Jurnal Penelitian Kimia, 14(2); 276.

Wang, P., X. Zhang, B. Zhou, F. Meng, Y. Wang, and G. Wen (2023). Recent Advance of Layered Double Hydroxides Materials: Structure, Properties, Synthesis, Modification and Applications of Wastewater Treatment. Journal of Environmental Chemical Engineering, 11(6); 111191.

Wibiyan, S., I. Royani, N. Ahmad, and A. Lesbani (2024a). Assessing the Efficiency, Selectivity, and Reusability of ZnAl-Layered Double Hydroxide and Eucheuma cottonii Composite in Removing Anionic Dyes from Wastewater. Inorganic Chemistry Communications, 170; 113347.

Wibiyan, S., I. Royani, A. Lesbani, et al. (2024b). Selective Adsorption of Cationic and Anionic Dyes Using Ni/Al Layered Double Hydroxide Modified with Eucheuma cottonii. Indonesian Journal of Material Research, 2(1); 1–6.

Wijaya, A., Z. A. Zahara, P. M. S. B. N. Siregar, N. Ahmad, A. Amri, N. R. Palapa, R. Mohadi, and A. Lesbani (2024). Cellulose-Supported Ni/Al Layered Double Hydroxide (LDH) as Unique Adsorbents for Malachite Green Dye Removal in Aqueous Solutions. Iranian Journal of Chemistry and Chemical Engineering, 43(4); 1566–1578.

Wongsa, P., P. Phatikulrungsun, and S. Prathumthong (2022). FTIR Characteristics, Phenolic Profiles and Inhibitory Potential Against Digestive Enzymes of 25 Herbal Infusions. Scientific Reports, 12(1); 6631.

Yang, J., G. Gao, Z. Zhu, and X. Yu (2022). Biochar Modified Co–Al LDH for Enhancing Photocatalytic Reduction CO2 Performance and Mechanism Insight. Research on Chemical Intermediates, 48(6); 2313–2323.

You, H., B. Huang, C. Cao, X. Liu, X. Sun, L. Xiao, J. Qiu, Y. Luo, Q. Qian, and Q. Chen (2021). Adsorption–Desorption Behavior of Methylene Blue onto Aged Polyethylene Microplastics in Aqueous Environments. Marine Pollution Bulletin, 167; 112287.

Zahid, S., W. Jamil, D. Q.-U.-N. Shumaila, and J. Shaikh (2024). Sorption of Methylene Blue Dye Through Synthesized and Modified Phenyl Pyruvate Zn Al Layered Double. Journal of Population Therapeutics & Clinical Pharmacology; 1625–1641.

Zehra, T., A. R. Safira, A. Fattah-alhosseini, M. Alkaseem, and M. Kaseem (2025). Decoration of CoFe-LDH/porous MgO Composite with ZrO2 Nanoparticles for Efficient Photocatalytic Removal of Indigo Carmine. Journal of Magnesium and Alloys, (in press).

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2025-03-22

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