Ca-Al Layered Double Hydroxides Pillared H4[α-PW12O40]•nH2O as Adsorbent Material for Cadmium (II) Removal from Aqueous Solution

Authors

  • Galuh Kirana Anggraini Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia
  • Ade Novitasari Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia
  • Amri Amri Research Center of Inorganic Materials and Coordination Complexes, Sriwijaya University, Palembang, 30139, Indonesia

DOI:

https://doi.org/10.26554/ijmr.20242235

Keywords:

Layered Double Hydroxides, POM, Adsorption, Cadmium

Abstract

Heavy metals in the environment can have a detrimental impact on human health. This study successfully used a new adsorbent material, specifically layered double hydroxide pillared with keggin polyoxometalate H4[α-PW12O40]•nH2O (Ca-Al/POM), to effectively remove cadmium (II) from aqueous solution. The Ca-Al/POM adsorbent has been thoroughly analyzed using X-ray diffraction and FT-IR. The findings showed an increase in the maximum adsorption capacity for cadmium (II) when using Ca-Al LDH intercalated with POM. The study of equilibrium adsorption isotherms showed that the Ca-Al/POM adsorbent effectively removed cadmium (II) and fit the Freundlich isotherm model. In addition, the adsorption kinetics study showed that the adsorption of cadmium (II) on Ca-Al/POM followed a pseudo second-order kinetics model.

References

Abdelmonem, H. A., T. F. Hassanein, H. E. Sharafeldin, H. Gomaa, A. S. A. Ahmed, A. M. Abdel-lateef, and A. H. Tilp (2024). Cellulose-Embedded Polyacrylonitrile/Amidoxime for the Removal of Cadmium (II) from Wastewater: Adsorption Performance and Proposed Mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 684; 133081

AitAghzzaf, A., Y. Zarki, B. Rhouta, A. Khalil, D. Veys-Renaux, H. Majdoub, and E. Rocca (2024). Intercalation of Decanoate Anions (C10) in Layered Double Hydroxide Mg-Al and Its Application as Controlled-Release Corrosion Inhibitor of Steel. Surface and Coatings Technology, 489; 131055

Allaoui, I., M. El Mourabit, B. Arfoy, M. Hadri, A. Barhoun, and K. Draoui (2024). Adsorption Equilibrium, Kinetic, and Thermodynamic Studies on the Removal of Paracetamol from Wastewater Using Natural and HDTMA-Modified Clay. Desalination and Water Treatment, 318; 100345

Cevallos-Mendoza, J. E., J. S. Cedeño-Muñoz, J. M. Navia-Mendoza, F. Figueira, C. G. Amorim, J. M. Rodríguez-Díaz, and M. C. B. S. M. Montenegro (2024). Development of Hybrid MIL 53(Al)@CBS for Ternary Adsorption of Tetracyclines Antibiotics in Water: Physical Interpretation of the Adsorption Mechanism. Bioresource Technology, 396

De Sá, F. P., B. N. Cunha, and L. M. Nunes (2013). Effect of pH on the Adsorption of Sunset Yellow FCF Food Dye into a Layered Double Hydroxide (CaAl LDH NO3). Chemical Engineering Journal, 215–216; 122–127

Debnath, S. and R. Das (2023). Strong Adsorption of CV Dye by Ni Ferrite Nanoparticles for Waste Water Purification: Fits Well the Pseudo Second Order Kinetic and Freundlich Isotherm Model. Ceramics International, 49(10); 16199–16215

Dou, D., D. Wei, X. Guan, Z. Liang, L. Lan, X. Lan, and P. Lan (2022). Adsorption of Copper (II) and Cadmium (II) Ions by In Situ Doped Nano-Calcium Carbonate High-Intensity Chitin Hydrogels. Journal of Hazardous Materials, 423; 127137

Gardner, E. A., S. K. Yun, T. Kwon, and T. J. Pinnavaia (1998). Layered Double Hydroxides Pillared by Macropolyoxometalates. Applied Clay Science, 13(5–6); 479–494

He, L., Y. Wang, C. Ding, G. Huang, X. Tu, Z. Zhou, and S. Zheng (2024). Selective and Efficient Immobilization of Cadmium in Soil by Layered Double Hydroxides Intercalated with the Mercaptosuccinic Acid. Science of the Total Environment, 937; 173473

Lesbani, A., T. Taher, N. R. Palapa, R. Mohadi, A. Rachmat, and Mardiyanto (2020). Preparation and Utilization of Keggin-Type Polyoxometalate Intercalated Ni–Fe Layered Double Hydroxides for Enhanced Adsorptive Removal of Cationic Dye. SN Applied Sciences, 2(3); 1–4

Li, Y., S. Wang, X. F. Ouyang, Z. Dang, and H. Yin (2024). Acetate Anions Intercalated Fe/Mg-Layered Double Hydroxides Modified Biochar for Efficient Adsorption of Anionic and Cationic Heavy Metal Ions from Polluted Water. Chemosphere, 362; 142652

Nkosi, N., N. D. Shooto, P. Nyamukamba, and P. M. Thabede (2024). Binary Adsorption of Toxic Nickel (II) and Cadmium (II) Ions from Aqueous Solution by Acid Modified Chilli Peppers. Energy Nexus, 15; 100313

Noorani Khomeyrani, S. F., B. Ghalami-Choobar, M. H. Ahmadi Azqhandi, and M. Foroughi (2022). An Enhanced Removal of Para-Nitrophenol (PNP) from Water Media Using CaAl-Layered Double Hydroxide-Loaded Magnetic g-CN Nanocomposite. Journal of Water Process Engineering, 46; 102516

Palapa, N. R. and A. Wijaya (2023). Layered Double Hydroxide Coated by Carbon-Based Material for Environmental Dye Pollutant. Indonesian Journal of Material Research, 1(3); 84–90

Palapa, N. R., A. Wijaya, P. M. S. B. N. Siregar, A. Amri, N. Ahmad, T. Taher, and A. Lesbani (2023). Adsorption of Fe(II) by Layered Double Hydroxide Composite with Carbon-Based Material (Biochar and Graphite): Reusability and Thermodynamic Properties. Indonesian Journal of Chemistry, 23(1); 101–112

Rezvani, M. A., A. Hemmatzadeh, M. S. Seyed Dorraji, N. Nourbakhsh, and G. Oroumi (2024). New Magnetic Nanocomposites Based on Hexaferrite and Keggin-Type Heteropolyanions: Synthesized and Characterized for Removal of Environmental Pollutants. Heliyon, 10(9); e30289

Siregar, P. M. S. B. N., A. Wijaya, Amri, J. P. Nduru, N. Hidayati, A. Lesbani, and R. Mohadi (2022). Layered Double Hydroxide/C (C=Humic Acid; Hydrochar) As Adsorbents of Cr(VI) Patimah. Science and Technology Indonesia, 7(1); 41–48

Wang, H., Y. Gao, W. Hu, Q. Wu, X. Zhong, B. Huang, and C. Wu (2023). Health Management of Cd-Contaminated Soil Using Ca Al Layered Double Hydroxide: Response of Different Vegetables. Agriculture, Ecosystems and Environment, 356; 108631

Xu, Y., H. Xia, Q. Zhang, G. Jiang, W. Cai, and W. Hu (2022). Adsorption of Cadmium (II) in Wastewater by Magnesium Oxide Modified Biochar. Arabian Journal of Chemistry, 15(9); 104059

Yuan, X., S. Ma, C. Zhao, X. Chen, Y. Zhou, S. Xi, and S. Liu (2024). Cadmium (II) Ion Adsorption of an Industrial Liquid Waste-Derived Ferric Oxide Loaded with Chitosan: Parameters Optimization, Isotherms, Kinetics and Thermodynamics. Desalination and Water Treatment, 319; 100578

Zhang, S., Y. Chen, J. Li, Y. Li, W. Song, X. Li, and H. Yu (2022). Highly Efficient Removal of Aqueous Cu(II) and Cd(II) by Hydrothermal Synthesized CaAl-Layered Double Hydroxide. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 641; 128584

Zhang, Y., X. Yue, W. Xu, H. Zhang, and F. Li (2019). Amino Modification of Rice Straw-Derived Biochar for Enhancing Its Cadmium (II) Ions Adsorption from Water. Journal of Hazardous Materials, 379; 120783

Downloads

Published

2024-07-26

Issue

Section

Articles