Reusable Heterogeneous Catalyst (M2+)Al-Layered Double Hydroxide used for Oxidative Desulfurization of 4,6-Dimethyldibenzothiophene
DOI:
https://doi.org/10.26554/ijmr.20231315Keywords:
Desulfurization, Layered Double Hydroxide, Catalyst, Heterogeneity, ReuseabilityAbstract
Catalyst material (M2+)Al-LDH was successfully prepared in this study. Characterisation analysis by XRD and FTIR. XRD analysis of Zn/Al-LDH, Mg/Al-LDH and Ni/Al-LDH showed agreement with pure LDH as seen from the JCPDS data and showed crystal forms similar to hydrotalcite, brucite and hydrotalcite respectively. FTIR analysis of the (M2+)Al-LDH material showed the presence of functional groups which explain the presence of O-H stretching, O-H bending, CO32- bonds and identified metal oxide (MO) groups from the synthesised LDH. (M2+)Al-LDH has the ability to act as a catalyst for excellent desulphurisation of 4,6-dimethyldibencothiophene with % conversion value above 90%. In addition, (M2+)Al-LDH is a heterogeneous and reusable catalyst.
References
Ahmad, N., M. Badaruddin, N. Yuliasari, F. S. Arsyad, and A. Lesbani (2022a). Highly Efficient Catalytic Oxidative Desulfurization of Dibenzothiophene using Layered Double Hydroxide Modified Polyoxometalate Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 17(4); 821–830
Ahmad, N., A. Wijaya, E. S. Fitri, F. S. Arsyad, R. Mohadi, and A. Lesbani (2022b). Catalytic Oxidative Desulfurization of Dibenzothiophene by Composites Based Ni/Al-Oxide. Science and Technology Indonesia, 7(3); 385–391
Ahmad, N., N. Yuliasari, F. S. Arsyad, I. Royani, R. Mohadi, and A. Lesbani (2023). Catalytic Oxidative Desulfurization of Dibenzothiophene by Heterogeneous M2+/Al-Layered Double Hydroxide (M2+= Zn, Mg, Ni) Modified Zinc Oxide. Iranian Journal of Catalysis, 13(1); 35–45
Al-Samhan, M., J. Al-Fadhli, A. M. Al-Otaibi, F. Al-Attar, R. Bouresli, and M. S. Rana (2022). Prospects of Refinery Switching from Conventional to Integrated: An Opportunity for Sustainable Investment in the Petrochemical Industry. Fuel, 310; 122161
Cao, Y., H. Wang, R. Ding, L. Wang, Z. Liu, and B. Lv (2020). Highly Efficient Oxidative Desulfurization of Dibenzothiophene Using Ni Modified MoO3 Catalyst. Applied Catalysis A: General, 589; 117308
Chang, H., H. Yi, and J. Zhang (2021). Preparation of a NiO Bi2WO6 Catalyst and Its Photocatalytic Oxidative Desulfurization Performance. Colloid and Interface Science Communications, 41; 100381
Houda, S., C. Lancelot, P. Blanchard, L. Poinel, and C. Lamonier (2018). Oxidative Desulfurization of Heavy Oils with High Sulfur Content: A Review. Catalysts, 8(9); 344
Huang, Y., X. Fan, H. Wang, Z. Li, D. Xiong, and Y. Pei (2023). Tuning Mg-Al Layered Double Hydroxides Synthesized from the Novel Ionic Liquid-Based Surfactant-Free Microemulsion for Efficiently Phosphate Removal in Aqueous Solutions. Journal of Molecular Liquids, 382; 121826
Intachai, S., T. Nakato, and N. Khaorapapong (2021). Zno Decorated on Low Carbonate NiAl Layered Double Hydroxide As Efficient Photocatalyst for Methyl Orange Degradation. Applied Clay Science, 201; 105927
Juleanti, N., N. R. Palapa, T. Taher, N. Hidayati, B. I. Putri, and A. Lesbani (2021). The Capability of Biochar-Based CaAl and MgAl Composite Materials As Adsorbent for Removal Cr(VI) in Aqueous Solution. Science and Technology Indonesia, 6(3); 196–203
Lin, Y., L. Feng, X. Li, Y. Chen, G. Yin, and W. Zhou (2020). Study on Ultrasound-Assisted Oxidative Desulfurization for Crude Oil. Ultrasonics Sonochemistry, 63; 104946
Liu, P., S. Yang, J. Hu, and H. Wang (2023). Numerical Analysis of SO2 Removal Characteristics in Industrial Flue Gas Desulfurization Reactor by Spray Drying Adsorption. Separation and Purification Technology, 323; 124475
Lozano-Lunar, A., R. Otero, J. I. Álvarez, J. R. Jiménez, and J. M. Fernández-Rodríguez (2023). Application of Layer Double Hydroxide in Cementitious Matrices for the Improvement of the Double Barrier Technique in the Immobilisation of Lead Waste. Applied Clay Science, 238; 106938
Lv, H., H. Rao, Z. Liu, Z. Zhou, Y. Zhao, H. Wei, and Z. Chen (2022). NiAl Layered Double Hydroxides with Enhanced Interlayer Spacing Via Ion-Exchange As Ultra-High Performance Supercapacitors Electrode Materials. Journal of Energy Storage, 52; 104940
Machrouhi, A., M. Khnifira, W. Boumya, M. Sadiq, M. Abdennouri, A. Elhalil, F. Mahjoubi, and N. Barka (2023). Experimental and Density Functional Theory Studies of Methyl Orange Adsorption on Ni-Al/LDH Intercalated Sodium Dodecyl Sulfate. Chemical Physics Impact, 6; 100214
Mahboob, I., I. Shafiq, S. Shafique, P. Akhter, M. Hussain, and Y. K. Park (2022). Effect of Active Species Scavengers in Photocatalytic Desulfurization of Hydrocracker Diesel Using Mesoporous Ag3VO4. Chemical Engineering Journal, 441; 136063
Mahjoubi, F. Z., A. Khalidi, M. Abdennouri, and N. Barka (2017). Zn–Al Layered Double Hydroxides Intercalated with Carbonate, Nitrate, Chloride and Sulphate Ions: Synthesis, Characterisation and Dye Removal Properties. Journal of Taibah University for Science, 11(1); 90–100
Malani, R. S., A. H. Batghare, J. B. Bhasarkar, and V. S. Moholkar (2021). Kinetic Modelling and Process Engineering Aspects of Biodesulfurization of Liquid Fuels: Review and Analysis. Bioresource Technology Reports, 14; 100668
Mallakpour, S., E. Azadi, and M. Dinari (2023). Removal of Cationic and Anionic Dyes Using Ca Alginate and Zn-Al Layered Double Hydroxide/metal-Organic Framework. Carbohydrate Polymers, 301; 120362
Miceli, M., P. Frontera, A. Macario, and A. Malara (2021). Recovery/reuse of Heterogeneous Supported Spent Catalysts. Catalysts, 11(5); 591
Mohadi, R., N. R. Palapa, S. Wibiyan, Mardiyanto, Rohmatullaili, E. S. Fitri, and A. Lesbani (2023). Catalytic Oxidative Desulfurization of 4-Methyldibenzothiophene by Ni/Al Modified Titanium Dioxide and Zinc Oxide. Science and Technology Indonesia, 8(3); 414–421
Pei, T., Y. Chen, H. Wang, and L. Xia (2023). Heteropolyacid Ionic Liquid-Based MCF: An Efficient Heterogeneous Catalyst for Oxidative Desulfurization of Fuel. Materials, 16(8); 3195
Polikarpova, P., A. Akopyan, A. Shlenova, and A. Anisimov (2020). New Mesoporous Catalysts with Brønsted Acid Sites for Deep Oxidative Desulfurization of Model Fuels. Catalysis Communications, 146; 106123
Priatna, S., Y. Hakim, S. Wibyan, S. Sailah, and R. Mohadi (2023). Interlayer Modification of West Java Natural Bentonite as Hazardous Dye Rhodamine B Adsorption. Science and Technology Indonesia, 8(2); 160–169
Privat, R., F. Garcia, J.-N. l. Jaubert, and M. Moliere (2009). Ethanol-Hydrocarbon Blend Vapor Prediction. In Turbo Expo: Power for Land, Sea, and Air, volume 48821. pages 377–387
Qin, J., H. Shi, Q. Lv, M. He, Y. Xu, M. Chen, X. Chen, J. Zhang, Y. Liu, and J. Yu (2023). Enhanced Adsorption Effect of Defect Ordering Mg/Al on Layered Double Hydroxides Nanosheets with Highly Efficient Removal of Congo Red. Materials & Design, 232; 112084
Rajendran, A., H. X. Fan, T. Y. Cui, J. Feng, and W. Y. Li (2022). Octamolybdates Containing MoV and MoVI Sites Supported on Mesoporous Tin Oxide for Oxidative Desulfurization of Liquid Fuels. Journal of Cleaner Production, 334; 130199
Subhan, S., A. U. Rahman, M. Yaseen, H. U. Rashid, M. Ishaq, M. Sahibzada, and Z. Tong (2019). Ultra-Fast and Highly Efficient Catalytic Oxidative Desulfurization of Dibenzothiophene at Ambient Temperature Over Low Mn Loaded Co-Mo/Al2O3 and Ni-Mo/Al2O3 Catalysts Using NaClO As Oxidant. Fuel, 237; 793–805
Tchalala, M., P. Bhatt, K. Chappanda, S. Tavares, K. Adil, Y. Belmabkhout, A. Shkurenko, A. Cadiau, N. Heymans, G. De Weireld, et al. (2019). Fluorinated MOF Platform for Selective Removal and Sensing of SO2 from Flue Gas and Air. Nature Communications, 10(1); 1328
Tran, H. N., C. C. Lin, and H. P. Chao (2018). Amino AcidsIntercalated Mg/Al Layered Double Hydroxides As Dual-Electronic Adsorbent for Effective Removal of Cationic and Oxyanionic Metal Ions. Separation and Purification Technology, 192; 36–45
Tripathi, N., R. S. Singh, and C. D. Hills (2019). Microbial Removal of Sulphur from Petroleum Coke (Petcoke). Fuel, 235; 1501–1505
Wang, H., B. Yuan, R. Hao, Y. Zhao, and X. Wang (2019). A Critical Review on the Method of Simultaneous Removal of Multi-Air-Pollutant in Flue Gas. Chemical Engineering Journal, 378; 122155
Wang, L., F. Ma, T. Niu, and C. Liang (2021). The Importance of Extreme Shock: Examining the Effect of Investor Sentiment on the Crude Oil Futures Market. Energy Economics, 99; 105319
Wei, X., D. Zheng, M. Zhao, H. Chen, X. Fan, B. Gao, L. Gu, Y. Guo, J. Qin, and J. Wei (2020). Cross Linked Polyphosphazene Hollow Nanosphere-Derived N/P-Doped Porous Carbon with Single Nonprecious Metal Atoms for the Oxygen Reduction Reaction. Angewandte Chemie, 132(34); 14747–14754
Wu, C., C. Chen, Z. Qi, J. Chen, Q. Wang, C. Ye, and T. Qiu (2023). Facile Synthesis of Efficient PentaethylenehexaminePhosphotungstic Acid Heterogeneous Catalysts for Oxidative Desulfurization. Chinese Journal of Chemical Engineering, 63; 140–147
Yuliasari, N., A. F. Badri, A. Wijaya, P. M. S. B. N. Siregar, R. Mohadi, and A. Lesbani (2022). Modification of Mg/Al-LDH Intercalated Metal Oxide (Mg/Al-Ni) to Improve the Performance of Methyl Orange and Methyl Red Dyes Adsorption Process. Science and Technology Indonesia, 7(3); 275–283
Zhang, Y., Z. Chen, X. Liu, Z. Dong, P. Zhang, J. Wang, Q. Deng, Z. Zeng, S. Zhang, and S. Deng (2019). Efficient SO2 Removal Using a Microporous Metal–Organic Framework with Molecular Sieving Effect. Industrial & Engineering Chemistry Research, 59(2); 874–882
Zhao, Z., Y. Zhang, W. Gao, J. Baleta, C. Liu, W. Li, W. Weng, H. Dai, C. Zheng, and X. Gao (2021). Simulation of SO2 Absorption and Performance Enhancement of Wet Flue Gas Desulfurization System. Process Safety and Environmental Protection, 150; 453–463
Zhou, X., X. Pei, R. Wang, and T. Zhao (2021). Catalytic Conversion for Hydrogen Sulfide. Aerosol and Air Quality Research, 21(9); 210065
Zhu, H., W. Lin, Q. Li, Y. Hu, S. Guo, C. Wang, and F. Yan (2020). Bipyridinium-Based Ionic Covalent Triazine Frameworks for CO2, SO2, and NO Capture. ACS Applied Materials & Interfaces, 12(7); 8614–8621
Zhu, H. Y., N. Y. Shi, D. Y. Liu, R. Li, J. G. Yu, Q. T. Ma, T. Y. Li, H. Ren, Y. Pan, and Y. Q. Liu (2023). New Insights into the Mechanism of Reactive Adsorption Desulfurization on Ni/ZnO Catalysts: Theoretical Evidence Showing the Existence of Interfacial Sulfur Transfer Pathway and the Essential Role of Hydrogen. Petroleum Science, 20(5); 3240–3250
Zhuang, X., Z. Zhang, Y. Wang, and Y. Li (2018). The Effect of Alternative Solvents to N-Hexane on the Green Extraction of Litsea Cubeba Kernel Oils As New Oil Sources. Industrial Crops and Products, 126; 340–346
